fresh piss is too good for this wastoid, but anything for you
I can't say for sure what the actual, factual turning point is, but I was once accidentally doused in urine that was approximately 24-48 hours old and had spent 24 of those hours in a mostly sealed jug in a hot car, and it was a terrible experience (a patient had collected a urine sample where they had to collect every urine void over a 24 hour period, and then bring it back for testing, but left it in their hot car for a day, which rendered the sample unusable, and the lid was not sealed and it got dumped on me)